Story of Rubber

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Raw material of the gum is created by rubber.  And it is a material that made of  combining gum and rubber. Lateks is a raw material and it is again created by petrol  and alcohol .

The plastic raw metarial rubber gained it’s value right after the process of Charles Goodyear’s hardening with sulphur and also with the contrubitions of the French scientsits in South America in 1736. So rubber took it’s value in Trade.

This method of the Charless Goodyear  has been improved in time. Especially by increasing  the speed of  dusting with sulphur  and also adding some chemicals materials in order to stand for getting breaked.

Rubber (tyre) at first; created as the combine of  sulphur and rubber materials.But after it gainedso much importance and  then people add some assorted chemicals in it and mix them together. Finally it became something better. On the other hand  with mixing colour material  they created the rubber in diferent colours.For being endurable against the effect of the weather, inside the rubber , the people also added, some assorted salts, amines and phenols that are made of plastic and rubber. These are created for supplying amorf carbon  and softness inside the rubber and by means of this  , in our day ; there are so many diferent technological rubbers created and some assorted parts can also be created from these rubbers.

Some special aimed rubbers are used in making the automobile tyres,höse and machine straps that requires  high pressure and at the same time  endurance . On the other hand  the battens  that are also  being used in cutting and plastering plates are so everlasting and elastical  and they can be produced with the high quality.

 

 

 

 

 

Rubber is the most used compound of the gum and is is never used alone. Generally is consist of 30/50 % Rubber.

Natural Rubber (NR)

Natural Rubber is produced from Rubber Tree that is called Hevea brasiliensis.

Natural Rubber composes of ;

% 30-40 rubber (cis-1,4 polyisoprene),

%2 resin,

% 60-65 water ,

% 2-5 lipid ve protein

Good Features

Bad Features

High Flexibility

Resistance to hydrocarbon

High Resistance

Air permeability

Low deformation and diffusion

Resistance air ,oxygen and ozone

Godd dynamic Features

It is a natural product so the price is changeable

Easy to process

 

Resistance to abrasion

 

Resistance to polar liquids

 

 

Natural Rubber is the raw material of the all kind of stuff such as hoses,lateks products, fan band, gum cylinder  gum gloves and etc...

Car tyre and Shoe sectors are the most widespread fields .

 

 

 

Synthetic Rubbers

Synthetic rubbers are the most used components in the gum compounds.

Styrene Butadiene Rubber (SBR):

Styrene and Butadiene is produced with cold type formula in a continuous system. It is a copolymer created with  Emulsion  Polymerisation and includes %22,5 - %24,5 bounded Stryene and it is used with general intent. Also it has got the resistance to high temperature, oil and the resolvents. In order to improve the physical features, it is necessary to add carbon black and the other charging materials on it.

Good Features

Bad Features

When reinforced, gives good physical features such as tearing ,abrasion or rupture.

Reinforcement is needed.

The features are good in low temperature.

Except abrasion the other features are lower than the Natural Rubber.

Cheap and easy to get.

Does not resist to Hydrocarbon

 

Does not resist to Oxgyen and Ozone but it is better than the Natural Rubber when  compared.

 

 

Styrene butadiene rubber is used in making of a car tyre, surrogate band , hose, shoe ground , mechanic stuff, auto mat.

 

 

 

 

Butyl Rubber (IIR): It has got a tight structure. Flexibility is low. Deformation is low  and permeability as well. It’s shape supplies crystallization in distention. It needs isopren groups for across connection, but it’s shape is  inerttir.

Good Features

Bad Features

Low permeability

Resiliency is low.

Heat and Ozone resistance

Fuel and oil resistance

Electrical isolation

Requires production in another line.

Abrasion Resistance

Vulkanisation time is long.

Cleavage resistance caused by flexibility.

Does not interfere to unsaturated polymer.

Chemical Resistance

 

It is used in the fields of low air permeability, such as  inner gum and roof covering and also in the fields of  applications that requires resistance to the outside conditions.

Polybutadiene (BR):

Turning feature around the double band, gathering itself in a short time, and it  requires reinforcement  because  the groups in open side cause crystallization. It supplies the reactivition of the double bands.

Good Features

Bad Features

Resiliency is low.

Resistance to tearing

Perfect abrasion resistance

Resistance to hydrocarbon

Electrical isolation feature

Electrical isolation feature

 

Heat and Ozone resistance

 

Mechanic feature

 

Reinforcement is needed.

Very good at auto back rubber. In order to get the best results it is used by comparing  with the other kind of rubbers. It is generally used in Auto Sector.

 

 

Ethylene Propylene (EPDM):

It is saturated shaped,briskness is low and time for gathering itself is  long. There can be  a unsaturated thermonomer fot the across connection.

Good Features

Bad features

High cushion and oil limitation,

EPDM requires special burner system. EPDM does not mix well with the other kind of rubbers.

Ageing and ozone resistance.

Resistance against hydrocarbon.

Processing  feature

Low resilience.

Dielectric feature.

Requires recinforcement.

 

Does not mix with the unsaturated polymers.

It is used in the production of good ageing, electric, the cable that requires resistance against the outer circumstances, radiator hose, profile.

Nitrile Rubber (NBR):

Generally consist of % 25–40 acrylonitrile. It has limited it’s briskness with hydrogen band. The groups in the open field prevents the crystallizations.C=N (acrylonitrile)  raises the resistance against oil.

Good Features

Bad Features

Resistanceagains oil and fuel

Requires the reinforcement.

Heat Resistance

Low heat features.

Permeability

Low resilience

Abrasion Resistance

Weak electric isolation.

It is generally used  for the products such as hose,gasket,carpet,flexible fuel and fuel warehouses that requires oil and fuel resistance.

 

Polyurethane Rubber (AU):

It has got a shape which has an endless variations. It looks like sponge when water and CO2 are detached. It’s shape gives oil and fuel resistance.But it hydrolysises.It’s  briskness is middle degreed.It can also reinforce itself.

Good Features

Bad Features

Abrasion

It hydrolysises

Teairng and rupture

Relisience is low

Oil and fuel

Expensive

Oxgyen and Ozone

 

Obtained in liquid form.

 

It is being used in charging discs that requires oil and abrasion resistance, gasket and carpets etc...

Neopren Rubber (EU):

Because of  generally 1.4 trans chlorine’s fixer affect, double bands are not re-active. Vulcanization can be  ready by adding 1.4. Chlorine oil makes a positive impact on oil and flaming. It’s route resembles to Natural Rubber in the way of it’s activity and briskness, but it is crystallize and this  makes a negative impact  on low temperature features.

Except auto tyre is looks like a natural rubber. It is used  in the places that requires fields,ozone, air, oil and fuel resistance. It’s  exercise field is limited  because it’s price is expensive  and it has  bad low temperature resistance.

Good Features

Bad Features

High Service Heat Interval

Expensive.

Resistance against the heat, air and oxgyen.

Low physical features

Good flexibility resistance.

Bad abrasion.

Good electron isolation feature, after getting burned it’s ashes keep showing isolation feature.

Bad oil and fuel resistance .

 

 

Can encounter hydrolysis

 

Expensive to process.

Silicone Rubbers (Si):

Because of  O-Si-O skeleton , briskness is high. The power between the chains are so low.When stretched it does not crystallizate. They are so decisive.

Good Features

Bad Features

Wide service heat

Expensive.

Resistance against heat, oxgyen and ozone.

Low physical features.

Good flexibility resistance

Bad abrasion.

Good electric isolation feature, after getting burned, it’s ashes  continues to show isolation features.

Bad oil and fuel resistance

 

 

 

Can encounter hydrolysis.

 

Expensive processing.

Basicly used in cable and impreviousness works. With their inert features they also can be used in medical applications.

Polyacrylates (ACM):

Because of their  cross bounded shape, their brisknes is  %5 lower. They do not crystallizate. As usual they are inert.

Good Features

Bad features

Resistance agains heat, ozone and oxygen.

Weat physical features

Oil and fuel resistance

Weak and low heat features

Good flexibility features

Weak water and acid resistance

Low  permeability

Expensive processing.

It has got a limited using field just like  gaskets that has the resistance against heat and carpets.

 

Floroelastormerler (FPM):

C-F groups has got good oil and fuel resistance, good heat resistance and gives low blazing-flaming up featureWhen tightened, it gets crystallize and it’s low heat flexibility is not good .

Good Features

Bad Features

Perfect heat resistance.

Weak low temperature features.

 It has got the resistance against oil, chemical meterials and fuel oil.

Expensive.

Resistance against oxgyen and ozone.

Expensive to be processed.

Low permeability.

 

Resistance agains flame.

 

It is used in the expensive  places  that requires high performance. For example: Special Gasket, Band, Hose, Military and Space Applications.

Gum compound is prepared in the compound machines and mixers. Different formulas are used for the products that will be produced. These formulas are evaluated elaborately.

PROCUT NAME

WORKING

TEMPERATURE

PHYSICAL AND  CHEMICAL FEATURES

[NBR] NITRILE RUBBER

-40 C +110 C

Has the resistance against Fuel, Diesel and some assorted industry gasses. It is the most preferred material in producing carpet.

[Si] SILICONE RUBBER

-60 C +200 C

The resistance of this metarial is low against tearing. But it  has high resistance against ozone and oxgyen effect.

[FPM] FLOROELASTOMERLER VITON RUBBER

-30 C +250 C

The resistance of this metarial is low against tearing but it has high resistance against ozone and oxgyen effect.

[AU] POLYURETHANE RUBBER

-30 C +90 C

It has got the resistance against air, ozone, pressure and oil, It has got a perfect resistance against high pressure,tearing and abrasion .

[EU] CR NEOPRENE RUBBER

-20 C +120 C

It has got the resistance against the patrol products in gas and liquid form,athmosphere circumstance , ozone, water and salty water. It is hard to burn.

[EPDM] EPDM RUBBER

-45 C +150 C

It has got the high resistance against the external factors,ozone,salty water and cold water.

[NR] NATURAL RUBBER

-60 C +90 C

It has got the resistance against some assorted acids and base,alcohol, cold and hot water. It is used in the places that requires high sensibility and mechanical features.